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A Guide to Organophosphorus Chemistry by Louis D. Quin PDF

By Louis D. Quin

ISBN-10: 0471318248

ISBN-13: 9780471318248

ISBN-10: 058527617X

ISBN-13: 9780585276175

An authoritative and complete advent to organophosphorus chemistry The huge, intriguing box of organophosphorus chemistry has grown enormously over the past few many years, with a wealth of possibilities for learn and functions improvement. A advisor to Organophosphorus Chemistry bargains chemists in academia and whole, up to date assurance of the basics with an eye fixed on destiny advancements during this zone. across the world well-known authority Louis D. Quin extends his skilled point of view and perception at the subject by:* Surveying an important phosphorus-containing sensible teams* together with consultant equipment of synthesis, plus references to special artificial techniques* Outlining advances in stereochemical points of phosphorus chemistry* protecting components of present learn, similar to strange coordination states, heterocycles, purposes of 31P-NMR, and different spectroscopic tools* offering quite a few references to big overview articles and up to date literature* featuring digital mechanisms and reactive intermediates the place validated* Discussing the significance of phosphorus compounds in dwelling structures and in agricultural applicationsLiberally illustrated with equations and structural formulation, A advisor to Organophosphorus Chemistry provides a nearly unheard of creation to the subject material, making it an integral educational device for aspiring chemists and training chemists alike.

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A Guide to Organophosphorus Chemistry by Louis D. Quin PDF

An authoritative and entire creation to organophosphorus chemistry The large, intriguing box of organophosphorus chemistry has grown greatly over the past few many years, with a wealth of possibilities for examine and purposes improvement. A advisor to Organophosphorus Chemistry deals chemists in academia and entire, up to date assurance of the basics with a watch on destiny advancements during this quarter.

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Extra resources for A Guide to Organophosphorus Chemistry

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Compounds with mixtures of these substituents are also well known. Alkoxy substituents have a special property, however; at high temperatures, or with catalysis by alkyl halides, they can undergo a rearrangement to phosphoryl compounds, a process referred to as the Michaelis-Arbusov rearrangement (Eq. 18). These rearrangements are of great practical synthetic importance and will be described more fully in chapter 5. Exposing 3-coordinate halides with P-alkyl groups to high temperatures can lead to decomposition by loss of hydrogen halide; aryl-substituted halides, however, are quite stable thermally.

References 1. A. R. Katritzky, C. W. Rees, and E. F. V. , Comprehensive Heterocyclic Chemistry II, Pergamon Press, Oxford, UK, 1996. 2. -H. -C. Chuang, K. C. -D. Lee, paper presented at the 1998 International Conference on Phosphorus Chemistry, Cincinnati, Ohio, July 1217, 1998. 3. R. Fathi, M. J. Rudolph, R. G. Gentles, R. Patel, E. W. MacMillan, M. S. Reitman, D. Pelham, and A. F. Cook, J. Org. Chem. 61, 5600 (1996). 4. M. M. Rauhut, Top. Phosphorus Chem. 1, 1 (1964); M. Grayson, Pure Appl. Chem.

The concept of the phosphoryl multiple bonding being derived from backbonding of oxygen electrons into a phosphorus 3d-orbital has been in wide use for many years. , those listed in reference 5), or in most older texts on inorganic chemistry. , reference 6), where the Page 14 power of modern computational methods has been employed, it has been shown that there is no role for d-orbitals in forming valence bonds, and the bonding picture assumed for many years for the phosphoryl group has to be abandoned.

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A Guide to Organophosphorus Chemistry by Louis D. Quin


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